Polyaromatic Hydrocarbons
A) US EPA List of Priority pollutants
contains 16 polyaromatic hydrocarbons. Reliable sublimation pressures and enthalpies for 9 compounds from this
list were already published in our laboratory:
naphthalene [1], acenaphthylene , fluorene, fluoranthene [2], acenaphthene, pyrene, phenanthrene, benzo[a]pyrene [3], anthracene [4].
Sublimation pressures for remaining 7 compounds are planned to be determined in near future:
chrysene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene,
dibenzo[a,h]anthracene, indeno[1,2,3-c,d]pyrene, benzo[g,h,i]perylene. We already measured heat capacities for several compounds from this list [5]
B) Also other PAHs and PAH-related distillation cuts were studied [6-10].
References
[1] Růžička, K.; Fulem,
M.; Růžička, V., Recommended Vapor Pressure of Solid Naphthalene. Journal of Chemical and Engineering Data 2005, 50, (6), 1956-1970 https://doi.org/10.1021/je050216m
[2]. Mahnel, T., V. Štejfa, M. Fulem, K. Růžička, Recommended vapor pressures for acenaphthylene, fluoranthene, and fluorene. Fluid Phase Equilibria, 2017. 434: p. 74-86. https://doi.org/10.1016/j.fluid.2016.11.012
[3] Růžička,
K.; Mokbel, I.; Majer, V.; Růžička, V.; Jose, J.; Zábranský, M., Description of
vapor-liquid and vapor-solid equilibria for a group of polycondensed compounds
of petroleum interest. Fluid Phase
Equilibria 1998, 148, (1-2),
107-137. https://doi.org/10.1016/S0378-3812(98)00200-3
(acenaphthene, pyrene,
phenanthrene, benzo[a]pyrene, vapor pressures measured in Lyon)
[4] Mahnel T.; Štejfa V.; Maryška M.; Fulem M.; Růžička K.,
Reconciled thermophysical data for anthracene. Journal of Chemical
Thermodynamics, 2019, 129, 61-72. https://doi.org/10.1016/j.jct.2018.08.034
[5] Mahnel T.;
Pokorný V.; Fulem M.;
Sedmidubský D.; Růžička K.,
Measurement of low-temperature heat capacity by relaxation technique:
Calorimeter performance testing and heat capacity of benzo[b]fluoranthene,
benzo[k]fluoranthene, and indeno[1,2,3-cd]pyrene. The Journal of Chemical
Thermodynamics, Volume 142, January 2020, 105964 https://doi.org/10.1016/j.jct.2019.105964
[6] Fulem, M.; Laštovka,
V.; Straka, M.; Růžička, K.; Shaw, J. M., Heat Capacities of Tetracene and
Pentacene. Journal of Chemical and
Engineering Data 2008, 53, (9),
2175-2181 https://doi.org/10.1021/je800382b
[7] Bazyleva,
A., M. Fulem, M. Becerra, B. Zhao, J.M. Shaw, Phase Behavior of
Athabasca Bitumen. Journal of Chemical and Engineering Data, 2011. 56(7):
p. 3242-3253. https://doi.org/10.1021/je200355f
[8] Sánchez-Lemus,
M.C., F. Schoeggl, S.D. Taylor, K. Růžička, M. Fulem, H.W. Yarranton, Deep-Vacuum
Fractionation of Heavy Oil and Bitumen, Part II: Interconversion Method.
Energy & Fuels, 2014. 28(5): p. 2866-2873. https://doi.org/10.1021/ef500490h
[9] Sanchez-Lemus, M.C., F. Schoeggl, S.D. Taylor, T. Mahnel, P.
Vrbka, K. Růžička, M. Fulem, H.W. Yarranton, Vapor pressure and
thermal properties of heavy oil distillation cuts. Fuel, 2016. 181:
p. 503-521. https://doi.org/10.1016/j.fuel.2016.04.143
[10] Štejfa V.,
Mahnel T., Skořepová
E., Rohlíček J., Eigner V., Schröder B., Růžička K., Fulem M.
A combined thermodynamic and crystallographic study of
1,3-diisopropylnaphthalene.
The Journal of Chemical Thermodynamics, 150, 2020, 106193, https://doi.org/10.1016/j.jct.2020.106193